賀鶴勇

物理化學

教授,博士生導師

heyonghe@fudan.edu.cn

上海市楊浦區淞滬路2005號 沐鸣平台江灣校區化學樓 A2007室

021-31243916

http://heyonghe-chem.fudan.edu.cn/

研究興趣

  • C1分子及低碳烴的催化轉化

  • 固體核磁共振等技術研究催化劑結構和催化反應機理

  • 酸催化

  • 多相催化加氫和手性加氫

  • 苯羥基化製苯酚催化劑研究

學術任職

  • 《催化學報》編委

  • 《波譜學報》編委

  • 中國化學會催化專業委員會委員

  • 中國物理學會波譜學專業委員會委員

  • 上海市化學化工學會副理事長

學習工作經歷

  • 1980.10-1984.6     沐鸣开户本科,獲得理學學士學位

  • 1984.6-1989.6     沐鸣开户助教

  • 1989.6-1990.6     英國倫敦帝國理工學院沐鸣开户訪問學者

  • 1990.7-1993.9     英國劍橋大學沐鸣开户研究生🤟🏻,獲得理學博士學位

  • 1993.10-1997.7     英國劍橋大學沐鸣开户固體核磁共振實驗室Manager

  • 1997.8-2000.3     英國利物浦大學沐鸣开户Leverhulme催化中心Principal Scientist

  • 2000.4起            沐鸣开户教授

授課情況

  • 固體核磁共振及其在結構表征和催化反應機理研究中的應用

  • 物理化學實驗

代表性論文或專著

  • Y.N. Wu, Y.Z. Wang, D.F. Huang, H.X. Ding, Y.H. Ren, Y. Zhang, B. Yue, H.Y. He, L. Ye. Direct quantification of oxygen vacancy on the TiO2 surface by 31P solid-state NMR. Chem Catal. 3, 100556 (2023).

  • Q.Y. Yao, L. Zhang, D.F. Huang, H.X. Ding, Y.H. Ren, X.Y. Chen, B. Yue, H.Y. He. MAS NMR studies on the formation and structure of oxygen vacancy on CeO2 surface under reducing atmosphere. J. Phys. Chem. C 127, 13021-13033 (2023).

  • X.K. Yang, H.X. Ding, Y.H. Ren, Y.K. Kang, Y.F. Li, Z.H. Li, B. Yue, H.Y. He, X.Y. Chen. Facet-dependent catalytic activity of shape-controllable palladium nanocrystals with clean surface in acetophenone selective hydrogenation. J. Catal. 428, 115159 (2023).

  • Q.Y. Yao, H.X. Ding, L. Zhang, W.H. Feng, J.W. Zhang, Y.H. Ren, L. Ye, X.Y. Chen, B. Yue, H.Y. He. MAS NMR studies on the formation and structure of oxygen vacancy on CeO2 {111} surface under reducing atmosphere. J. Phys. Chem. C 128, 9962-9972 (2024).

  • J.F. Zhou, Y.T. Miao, H.X. Ding, Y.H. Ren, L. Ye, B. Yue, H.Y. He. Direct and stable hydrogenation of CO2 to aromatics over a tandem catalyst Zn0.1Ti0.9Ox/HZSM-5. iScience, 24, 110360 (2024).

  • L. Z., J.J. Su, C. Liu, S. Liu, H.B. Zhou, W.Q. Jiao, Y.F. Hu, F. Xiong, Y.Q. Lu, Y.C. Ye, X.S. Zheng, Y.D. Wang, H.Y. He. Surface self-cleaning effect of bifunctional catalyst to boost the high yield production of aromatics directly from syngas. ACS Catal. 14, 8972-8982 (2024).

  • J.W. Zhang, H.X. Ding, H.H. Hui, Q.Y. Yao, W.H. Feng, T.X. Chen, T.W.B. Lo, Y.H. Ren, L. Ye, B. Yue, H.Y. He. Confined Cu single sites in ZSM-5 for photocatalytic hydroxylation of benzene to phenol. Small DOI10.1002/smll.202405150 (2024).

  • X. Chen, D.F. Huang, L.L. He, L. Zhang, Y.H. Ren, X.Y. Chen, B. Yue, H.Y. He. The effect of adsorbed water molecules on the surface acidity of niobium and tantalum oxides studied by MAS NMR. J. Phys. Chem. C. 125, 9330-9341 (2021).

  • C. Liu, J.J. Su, S. Liu, H.B. Zhou, X.H. Yuan, Y.C. Ye, Y. Wang, W.Q. Jiao, L. Zhang, Y.Q. Lu, Y.D. Wang, H.Y. He, Z.K. Xie. Insights into the key factor of zeolite morphology on selective conversion of syngas to light aromatics over Cr2O3/ZSM-5 catalyst. ACS Catal. 10, 15227-15237 (2020).

  • J.F. Zhou, L. Ye, D.F. Huang, M.Y. Wang, Y.H. Ren, B. Yue, H.Y. He. The synergy of modulated surface polarity and oxygen vacancy for CO2 to methanol over Zn(δ−)-Ti(δ+)Ovacancy. J. Energy Chem. 56, 449-454 (2020).

  • Y.N. Wu, X. Chen, D.F. Huang, L. Zhang, Y.H. Ren, G.F. Tang, X.Y. Chen, B. Yue, H.Y. He. The study on acidity of sulfated CuO layers grown by surface reconstruction of Cu2O exposed with specific facets. Catal. Sci. & Techno. 10, 3985-3993 (2020).

  • X. Li, Y.H. Ren, Z.W. Weng, B. Yue, H.Y. He. Stabilization of high-valent Cu3+ in a Keggin-type polyoxometalate. Chem. Commun. 56, 2324-2327 (2020).

  • X.Y. Gao, X.Y. Chen, Z.H. Li, H.Y, He. Direct synthesis of in-situ chirally modified palladium nanocrystals without capping agents and their application in heterogeneous enantioselective hydrogenations. ACS Catal. 9, 6100-6110 (2019).

  • Y.Y. Fu, L. Zhang, B. Yue, X.Y. Chen, H.Y. He. Simultaneous characterization of solid acidity and basicity of metal oxide catalysts via solid state NMR technique. J. Phys. Chem. C 122, 24094-24102 (2018).

  • N. Su, X.Y. Gao, X.Y. Chen, B. Yue, H.Y. He. The enantioselective hydrogenation of acetophenone over Pd concave tetrahedron nanocrystals affected by the residual adsorbed capping agent polyvinylpyrrolidone (PVP). J. Catal. 367, 244-251 (2018).

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